Drift and clustering of daughter negative ions of H_2O in parent gas

摘要

The mobility of daughter negative ions of H_2O in parent gas has been measured with a pulsed Townsend technique over the density-reduced field strength, E/N, range 9-100Td and a pressure range 2-16Torr. It has been found that the mobility of the anions is dependent on the gas pressure. Using a transport theory considering the influence of the permanent dipole field of H_2O, we have found that the pressure-dependent mobilities can be associated with a series of cluster ions of the type OH~-(H_2O)_n (n=1-3), with the mass of the cluster species increasing with the total gas pressure. Also, the mobility of H~- and OH~- could be estimated. Using a Townsend avalanche simulator we have been able to explain the measured ionic currents in terms of an ion-molecule reaction scheme with a single set of swarm and reaction coefficients for each value of the density-reduced field strength, E/N, at several pressures. Regarding the positive ions, the only drifting ion is H_3O~+, the mobility of which could be estimated. The rate constants relative to the formation of the OH~-(H_2O)_n (n=1-3) species were also derived from this study.