Synthesis, characterization, single crystal X-ray structure determination and packing analysis of thallium(I) anthracene-9-carboxylate, [Tl-4(H2O)(2)(anthracene-9-carboxylate)(4)]

摘要

A new tetranuclear thallium complex, [Tl-4(H2O)(2)(anthracene-9-carboxylate)(4)] was isolated by reaction of hot aqueous solution of thallium(1)sulphate with sodium salt of anthracene-9-carboxylic acid in water taken in appropriate stoichiometric ratio. The newly synthesized complex was characterized by elemental analysis, thermogravimetric analysis, spectroscopic studies (FT-IR, UV-Visible, and multinuclear NMR). Complex crystallizes in monoclinic crystal system with P2(1) space group. X-ray crystal structure determination revealed the presence of neutral centrosymmetric tetranuclear complex which contains two symmetry independent thallium cations. Tl1 is four-coordinate and bonded to three different anthracene-9-carboxylate anions. The other thallium cation, Tl2, is three-coordinate, being surrounded by two carboxylate oxygen atoms from two different ligands; anthracene-9-carboxylate and a water molecule. The crystal lattice is stabilized by C-H/O-H center dot center dot center dot O hydrogen bonding and cation center dot center dot center dot pi it interactions. (C) 2014 Elsevier B.V. All rights reserved.