Synthesis and characterization of a copper(II) complex of a ONN donor Schiff base ligand derived from pyridoxal and 2-(pyrid-2-yl)ethylamine-A novel pyridoxal based fluorescent probe

摘要

The title complex, Cu(LH)Cl_2 is the first copper(II) complex with a Schiff base derived from pyridoxal and 2-(pyrid-2-yl)ethylamine. The central metal lies in a distorted square pyramidal environment with basal plane occupied by the tridentate ONN donor ligand and a Cl atom. The apical position is occupied by another Cl atom. The existence of two different kinds of H-bonds stabilize the network that propagates as parallel layers along crystallographic b axis. The compound exhibits an irreversible CuII/CuI couple in DMF. As pyridoxal containing moieties are fluorescent in nature, its potential as a fluorescent probe is cultivated. Copper(II) ion effectively quenches the fluorescence of HL and the association constant for Cu(II) was estimated to be 10.8 × 10~4 M~(-1) in methanol by the linear Benesi-Hildebrand equation.