Structural, optical and magnetic properties of Co-doped ZnO nanorods prepared by hydrothermal method

摘要

Zn_(1-x)Co_xO (0 <= x <= 0.06) nanorods were fabricated by hydrothermal method. The effect of Co doping on the morphology, crystalline structure, optical and magnetic properties of the samples was investigated. The length of obtained ZnO nanorods increases with the increasing Co concentration. Based on the results of X-ray diffraction and Raman spectra, it is confirmed that a small amount of Co ions are incorporated into ZnO lattice. The segregated phase of Co_3O_4 was detected at x > 0.01. The absorption and photolumi nescence spectra reveal the d-d electronic transitions of tetrahedrally coordinated Co~(2+) in ZnO host. Co doping induces fluorescent quenching of the visible emission bands related to surface states and defect states in the Co-doped ZnO nanorods. Weak room temperature ferromagnetism was observed in the sam?ples with x = 0.01 and then paramagnetic characteristics of the samples with x > 0.01.