首页> 外文期刊>Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics >Effect of Tb~(3+) concentration and sensitization of Ce~(3+) on luminescence properties of terbium doped phosphate scintillating glass
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Effect of Tb~(3+) concentration and sensitization of Ce~(3+) on luminescence properties of terbium doped phosphate scintillating glass

机译:Tb〜(3+)浓度和Ce〜(3+)敏化对掺do磷酸盐闪烁玻璃发光性能的影响

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摘要

Phosphate glasses doped with different concentrations of Ce~(3+) and Tb~(3+) were prepared by high temperature melting method. Effects of Tb~(3+) concentration and sensitization of Ce~(3+) on photoluminescence and radio-luminescence properties of terbium doped phosphate glass have been investigated by absorption, excitation and emission spectroscopy. Results showed the phosphate glass exhibit high broad absorption band attribute to the allowed 4f~8-4f~7 5d transition of Tb~(3+), which is beneficial for the 542 nm emission of Tb~(3+). It is found that the emission intensity of Tb~(3+) at 542 nm increased as the concentration of Tb~(3+) and Ce~(3+)increasing.
机译:通过高温熔融法制备了掺杂不同浓度的Ce〜(3+)和Tb〜(3+)的磷酸盐玻璃。通过吸收,激发和发射光谱研究了Tb〜(3+)的浓度和Ce〜(3+)的敏化度对掺phosphate磷酸盐玻璃的光致发光和辐射致发光性能的影响。结果表明,磷酸盐玻璃具有较高的宽吸收带,这归因于Tb〜(3+)的4f〜8-4f〜7 5d跃迁,有利于Tb〜(3+)的542 nm发射。研究发现,随着Tb〜(3+)和Ce〜(3+)浓度的增加,Tb〜(3+)在542 nm处的发射强度增加。

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