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Properties of polycarbonate/acrylonitrile-butadiene-styrene/talc composites

机译:聚碳酸酯/丙烯腈-丁二烯-苯乙烯/滑石粉复合材料的性能

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摘要

The morphology, tensile, impact properties, and thermal expansion behavior of polycarbonate (PC)/acrylonitrile-styrene-butadiene (ABS)/talc composites with different compositions and mixing sequences were investigated. From the studies of morphology of the PC/ABS/talc composites, it was observed that some talc particles were located in both the PC and the ABS phases of the blend but most were at the interface between the PC and ABS phases for every mixing sequence. Aspect ratios of the talc particles determined by TEM image analysis reasonably matched values computed from tensile modulus using composite theory. The thermal expansion behavior, or CTE values, was not significantly influenced by the mixing sequence. The impact strength of the PC/ABS/talc composites depended significantly on the mixing sequence; a premix with PC gave the poorest toughness. The molecular weight of the PC in PC/talc composites was found to be significantly decreased. It appears that the impact strength of the PC/ABS/talc composites is seriously compromised by the degradation of the PC caused by talc.
机译:研究了不同组成和混合顺序的聚碳酸酯(PC)/丙烯腈-苯乙烯-丁二烯(ABS)/滑石复合材料的形貌,拉伸性能,冲击性能和热膨胀行为。通过对PC / ABS /滑石复合材料的形态研究,可以观察到某些滑石颗粒位于共混物的PC和ABS相中,但对于每个混合顺序,大多数滑石颗粒位于PC和ABS相之间的界面。通过TEM图像分析确定的滑石颗粒的长宽比与使用复合理论从拉伸模量计算出的值合理匹配。热膨胀行为或CTE值不受混合顺序的影响。 PC / ABS /滑石复合材料的冲击强度在很大程度上取决于混合顺序。与PC预混的韧性最差。发现PC /滑石复合物中PC的分子量显着降低。似乎由于滑石引起的PC降解,严重损害了PC / ABS /滑石复合材料的冲击强度。

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