Melt rheological properties of reactive compatibilized HDPE/PET blends

摘要

Melt rheological properties of high density polyethylene and poly(ethylene terephthalate) (HDPE/PET) blends compatibilized by an ethylene-butyl acrylateglycidyl methacrylate terpolymer (EBAGMA) were studied by means of a HAAKE torque rheometer and a capillary rheometer. The phase morphology of the blends was evaluated by a scanning electron microscope (SEM). The results showed that the melts of blends behave pseudoplasticity. The addition of EBAGMA strengthens the interfacial adhesion between HDPE and PET and improves the phase dispersion due to reactive compatibilization. It was observed that the balance torque, melt viscosity, and sensitivity of melt viscosity to shear rate of the melts increase with increasing content of EBAGMA, but the melt flow index and activation energy decrease. At the same time, the plasticizing time is shortened indicating that the processability of the compatibilized blends has been improved. (c) 2008 Wiley Periodicals, Inc.