Thermal properties and crystallization behavior of ultrafine fully-vulcanized powdered rubber particle toughened polypropylene

摘要

Thermal properties and crystallization-behavior of ultrafine fully-vulcanized powdered rubber (UFPR) toughened poly propylene (PP) were studied by Differential scanning calorimetry (DSC) and Wide angle X-ray diffraction (WAXD) measurements. It was found that the fraction of beta-form in the PP crystal increased at first, then sharply deceased up to zero with increasing UFPR content. This trend did not rely on isothermal crystallization temperature. Moreover, DSC measurements implied that UFPR particles addition affected both isothermal and nonisothermal crystallization behaviors, including the crystallization temperature and the half-time of crystallization. Furthermore, WAXD test results indicated that the addition of UFPR induced the orientation of the crystallites more or less. (C) 2008 Wiley Periodicals, Inc.