首页> 外文期刊>Dalton transactions: An international journal of inorganic chemistry >Synthesis, crystal structure and photocatalytic properties of an unprecedented arsenic-disubstituted Lindqvist-type peroxopolyoxoniobate ion: {As_2Nb_4(O_2)_4O_(14)H_(1.5)}~(4.5-)
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Synthesis, crystal structure and photocatalytic properties of an unprecedented arsenic-disubstituted Lindqvist-type peroxopolyoxoniobate ion: {As_2Nb_4(O_2)_4O_(14)H_(1.5)}~(4.5-)

机译:前所未有的砷二取代的Lindqvist型过氧聚氧杂酸根离子的合成,晶体结构和光催化性能:{As_2Nb_4(O_2)_4O_(14)H_(1.5)}〜(4.5-)

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摘要

An unprecedented arsenic-disubstituted Lindqvist-type peroxopolyoxoniobate Cs_(2.5)Na_2{As_2Nb_4(O_2)_4O_(14)H_(1.5)}?11H_2O has been successfully synthesized and characterized. The photocatalytic activity of the cluster for H2 evolution from water is investigated by irradiating with a 300 W Xe lamp, which shows a certain photocatalytic water splitting activity.
机译:已经成功地合成并表征了前所未有的砷二取代的Lindqvist型过氧聚氧氧杂酸盐Cs_(2.5)Na_2 {As_2Nb_4(O_2)_4O_(14)H_(1.5)}?11H_2O。通过用300 W Xe灯照射,研究了团簇从水中释放H2的光催化活性,该灯显示出一定的光催化水分解活性。

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