Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex

Polly L. Arnold; Isobel A. Marr; Sergey Zlatogorsky; Ronan Bellabarba; Robert P. Tooze

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Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex

机译：N-杂环卡宾配合物活化二氧化碳和二硫化碳

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A Sc NHC complex readily activates three equivalents of CO_2 showing 'Frustrated Lewis Pair' type reactivity with each metal-carbene bond, but whilst CS_2 is also activated by the labile carbenes, no metal involvement is observed.

机译：Sc NHC络合物很容易活化三当量的CO_2，与每个金属碳烯键显示出“沮丧的路易斯对”型反应性，但是CS_2也被不稳定的卡宾活化，但未观察到金属参与。

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《Dalton transactions: An international journal of inorganic chemistry》 |2014年第1期|共4页
作者
Polly L. Arnold; Isobel A. Marr; Sergey Zlatogorsky; Ronan Bellabarba; Robert P. Tooze;
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正文语种 eng
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Activation; complex; observed;

机译：激活;复杂;观察到;

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1. Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex [J] . Polly L. Arnold, Isobel A. Marr, Sergey Zlatogorsky, Dalton transactions: An international journal of inorganic chemistry . 2014,第1期

机译：N-杂环卡宾配合物活化二氧化碳和二硫化碳
2. Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene- Isoquinoline Complex [J] . V. Sara Thoi, Nikolay Kornienko, Charles G. Margarit, Journal of the American Chemical Society . 2013,第38期

机译：可见光光氧化还原催化：镍N-杂环碳-异喹啉配合物选择性将二氧化碳还原为一氧化碳
3. Carbon monoxide and carbon dioxide insertion chemistry of f-block N-heterocyclic carbene complexes [J] . Arnold P.L., Turner Z.R., Germeroth A.I., Dalton transactions: An international journal of inorganic chemistry . 2013,第5期

机译：f嵌段N杂环卡宾配合物的一氧化碳和二氧化碳插入化学
4. Silica Gel-supported N-heterocyclic Carbene Acting as Carbon Dioxide Absorbent [C] . The 12th Asian Pacific Confederation of Chemical Engineering Congress(第十二届亚太化工联盟大会暨化工展览会)论文集 . 2008

机译：硅胶负载的N-杂环卡宾作为二氧化碳的吸收剂
5. Site- and enantioselective carbon-carbon and carbon-boron bond forming reactions catalyzed by copper-, magnesium-, zinc-, or aluminum-based N-heterocyclic carbene complexes. [D] . Lee, Yunmi. 2010

机译：基于铜，镁，锌或铝的N-杂环卡宾配合物催化的位和对映选择性碳-碳和碳-硼键形成反应。
6. Selective and catalytic carbon dioxide and heteroallene activation mediated by cerium N-heterocyclic carbene complexes [O] . Polly L. Arnold, Ryan W. F. Kerr, Catherine Weetman, 2018

机译：铈N-杂环卡宾配合物介导的选择性催化二氧化碳和杂戊烯活化
7. Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex [O] . Arnold, Polly L., Marr, Isobel A., Zlatogorsky, Sergey, 2014

机译：通过钪N-杂环卡宾配合物活化二氧化碳和二硫化碳
8. Visible-Light Photoredox Catalysis: Selective Reduction of Carbon Dioxide to Carbon Monoxide by a Nickel N-Heterocyclic Carbene-Isoquinoline Complex. [R] . Sara, V., Kornenko, N., Margarit, C. G., 2013

机译：可见光光催化氧化催化：用镍N-杂环卡宾 - 异喹啉配合物选择性还原二氧化碳为一氧化碳。

Activation of carbon dioxide and carbon disulfide by a scandium N-heterocyclic carbene complex

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