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首页> 外文期刊>The journal of physical chemistry, C. Nanomaterials and interfaces >Size-Dependent Optical Properties of Zinc Blende Cadmium Telluride Quantum Dots
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Size-Dependent Optical Properties of Zinc Blende Cadmium Telluride Quantum Dots

机译:锌共混碲化镉量子点的尺寸依赖性光学性质

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摘要

We analyze the optical properties of CdTe quantum dots, including the sizing curve, the absorption coefficient, and the oscillator strength of the band gap transition, by combining absorption spectroscopy, elemental analysis, and electron microscopy imaging. At short wavelengths, the absorption coefficient spectrum is still affected by quantum confinement, yet a largely constant value, close to that of bulk CdTe, is found at around 410 nm. At shorter wavelengths, remaining quantum confinement effects on the CdTe E1 transition are present even for the largest quantum dots studied (11 nm). For the band gap transition, we find an integrated absorption coefficient μ_(gap) that scales almost proportionally to the inverse of the quantum dot volume. Especially for the smaller diameters, deviations up to a factor of 3 are found as compared to widely used literature values. The corresponding oscillator strength f_(gap) is almost size-independent in the diameter range 3—7 nm. The correspondence between radiative lifetimes predicted based on f_(gap), and literature values is discussed.
机译:通过结合吸收光谱,元素分析和电子显微镜成像,我们分析了CdTe量子点的光学特性,包括尺寸曲线,吸收系数和带隙跃迁的振荡器强度。在短波长下,吸收系数谱仍然受到量子限制的影响,但在410 nm附近发现了一个接近常数CdTe的很大的常数。在较短的波长下,即使对于研究的最大量子点(11 nm),也存在对CdTe E1跃迁的剩余量子限制效应。对于带隙跃迁,我们发现积分吸收系数μ_(gap)几乎与量子点体积的倒数成比例。特别是对于较小的直径,与广泛使用的文献值相比,发现偏差高达3倍。在3-7 nm的直径范围内,相应的振荡器强度f_(gap)几乎与尺寸无关。讨论了基于f_(gap)预测的辐射寿命与文献值之间的对应关系。

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