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Superfluid response of two-dimensional parahydrogen clusters in confinement

机译:封闭中二维对氢簇的超流体响应

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We study by computer simulations the effect of confinement on the superfluid properties of small two-dimensional (2D) parahydrogen clusters. For clusters of fewer than twenty molecules, the superfluid response in the low temperature limit is found to remain comparable in magnitude to that of free clusters, within a rather wide range of depth and size of the confining well. The resilience of the superfluid response is attributable to the "supersolid" character of these clusters. We investigate the possibility of establishing a bulk 2D superfluid "cluster crystal" phase of p-H-2, in which a global superfluid response would arise from tunnelling of molecules across adjacent unit cells. The computed energetics suggests that for clusters of about ten molecules, such a phase may be thermodynamically stable against the formation of the equilibrium insulating crystal, for values of the cluster crystal lattice constant possibly allowing tunnelling across adjacent unit cells. (C) 2015 AIP Publishing LLC.
机译:我们通过计算机模拟研究限制对小型二维(2D)对氢簇的超流体性质的影响。对于少于二十个分子的团簇,发现低温限制中的超流体响应在相当大的深度和尺寸范围内都可以与自由团簇保持相当的大小。超流体响应的弹性可归因于这些簇的“超固体”特征。我们调查建立p-H-2的大体积2D超流体“簇晶体”相的可能性,其中全局超流体响应将由跨相邻单位细胞的分子隧穿引起。计算出的能量学表明,对于大约十个分子的簇,这样的相对于平衡绝缘晶体的形成可能是热力学稳定的,因为簇晶格常数的值可能允许在相邻的晶胞中隧穿。 (C)2015 AIP Publishing LLC。

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