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Surveying the free energy landscapes of continuum models: Application to soft matter systems

机译:测量连续模型的自由能态势:在软物质系统中的应用

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摘要

A variety of methods are developed for characterising the free energy landscapes of continuum, Landau-type free energy models. Using morphologies of lipid vesicles and a multistable liquid crystal device as examples, I show that the methods allow systematic study of not only the most relevant minimum energy configurations, but also the transition pathways between any two minima, as well as their corresponding energy barriers and transition state configurations. A global view of the free energy landscapes can then be visualized using either a disconnectivity graph or a network representation. Different forms of free energy functionals and boundary conditions can be readily implemented, thus allowing these tools to be utilised for a broad range of problems. (C) 2015 AIP Publishing LLC.
机译:开发了多种方法来表征连续介质的Landau型自由能模型的自由能态。以脂质囊泡和多稳态液晶器件的形态为例,我证明了这些方法不仅可以对最相关的最小能量构型进行系统研究,而且还可以对任何两个极小值之间的过渡途径及其相应的能垒进行系统研究。过渡状态配置。然后,可以使用断开连接图或网络表示来可视化自由能态势的全局视图。不同形式的自由能功能和边界条件可以很容易地实现,从而使这些工具可以用于广泛的问题。 (C)2015 AIP Publishing LLC。

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