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首页> 外文期刊>The Journal of Chemical Physics >Phase diagrams of mixtures of a polymer and a cholesteric liquid crystal under an external field
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Phase diagrams of mixtures of a polymer and a cholesteric liquid crystal under an external field

机译:外场下聚合物与胆甾型液晶混合物的相图

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摘要

We present a mean field theory to describe phase behaviors in mixtures of a polymer and a cholesteric liquid crystal under an external magnetic or electric field. Taking into account a chiral coupling between a polymer and a liquid crystal under the external field, we examine twist-untwist phase transitions and phase separations in the mixtures. It is found that a cholesteric-nematic phase transition can be induced by not only the external field but also concentration and temperature. Depending on the strength of the external field, we predict cholesteric-paranematic (Ch+pN), nematic-paranematic (N+pN), cholesteric-nematic (Ch+N) phase separations, etc., on the temperature-concentration plane. We also discuss mixtures of a non-chiral nematic liquid crystal and a chiral dopant. (C) 2014 AIP Publishing LLC.
机译:我们提出一种平均场理论,以描述在外部磁场或电场作用下聚合物和胆甾型液晶混合物的相行为。考虑到外部电场下聚合物和液晶之间的手性偶联,我们研究了混合物中扭曲-未扭曲的相变和相分离。已经发现胆甾型向列相转变不仅可以由外场引起,而且可以由浓度和温度引起。根据外部电场的强度,我们可以预测温度浓度平面上的胆甾型-向列相(Ch + pN),向列型-副向列相(N + pN),胆甾型-向列相(Ch + N)等分离。我们还讨论了非手性向列液晶和手性掺杂剂的混合物。 (C)2014 AIP Publishing LLC。

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