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Crystallization in glassy suspensions of hard ellipsoids

机译:硬椭球状玻璃状悬浮液中的结晶

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We have carried out computer simulations of overcompressed suspensions of hard monodisperse ellipsoids and observed their crystallization dynamics. The system was compressed very rapidly in order to reach the regime of slow, glass-like dynamics. We find that, although particle dynamics become sub-diffusive and the intermediate scattering function clearly develops a shoulder, crystallization proceeds via the usual scenario: nucleation and growth for small supersaturations, spinodal decomposition for large supersaturations. In particular, we compared the mobility of the particles in the regions where crystallization set in with the mobility in the rest of the system. We did not find any signature in the dynamics of the melt that pointed towards the imminent crystallization events.
机译:我们已经对硬质单分散椭球体的超压缩悬浮液进行了计算机模拟,并观察了它们的结晶动力学。为了迅速达到类似于玻璃的动态状态,系统被非常快速地压缩。我们发现,尽管粒子动力学变得次扩散,并且中间散射功能明显形成了肩峰,但结晶通过通常的情况进行:小过饱和的成核和生长,大过饱和的旋节线分解。特别是,我们将结晶进入的区域中粒子的迁移率与系统其余部分中的迁移率进行了比较。我们在熔体动力学中没有发现任何迹象表明即将发生结晶事件。

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