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A one-dimensional model with water-like anomalies and two phase transitions

机译:具有水样异常和两个相变的一维模型

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We investigate a one-dimensional model that shows several properties of water. The model combines the long-range attraction of the van der Waals model with the nearest-neighbor interaction potential by Ben-Naim, which is a step potential that includes a hard core and a potential well. Starting from the analytical expression for the partition function, we determine numerically the Gibbs energy and other thermodynamic quantities. The model shows two phase transitions, which can be interpreted as the liquid-gas transition and a transition between a high-density and a low-density liquid. At zero temperature, the low-density liquid goes into the crystalline phase. Furthermore, we find several anomalies that are considered characteristic for water. We explore a wide range of pressure and temperature values and the dependence of the results on the depth and width of the potential well.
机译:我们研究了显示水的几种属性的一维模型。该模型将范德华模型的远程吸引力与Ben-Naim的最近邻居相互作用势相结合,这是一个包含硬核和势阱的阶梯势。从分配函数的解析表达式开始,我们从数值上确定吉布斯能量和其他热力学量。该模型显示了两个相变,可以解释为液-气转变以及高密度和低密度液体之间的转变。在零温度下,低密度液体进入结晶相。此外,我们发现了一些异常现象,这些异常被认为是水的特征。我们探索了广泛的压力和温度值,以及结果对势阱深度和宽度的依赖性。

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