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首页> 外文期刊>The Journal of Chemical Physics >Strong stretching theory for diblock copolymers in thin films under application of electric fields
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Strong stretching theory for diblock copolymers in thin films under application of electric fields

机译:电场作用下薄膜中二嵌段共聚物的强拉伸理论

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We investigate the microphases of asymmetric AB diblock copolymers confined to thin films in the strong segregation limit under the application of electric fields. We evaluate the free energy of a given set of possible phases and present phase diagrams for diblock copolymers with a cylindrical bulk phase in dependence of the film thickness and the attraction between the confining walls and the A or B monomers. This is done for different field strengths and volume fractions. We find that with increasing field strength structures show a preference for alignment with the field. The alignment is stronger when the permittivity of the minority monomer is larger than that of the majority monomer. Depending on the strength of the wall potential and the film thickness, the walls can become completely wetted by the minority monomer. [http://dx.doi.org/10.1063/1.4738594]
机译:我们在电场的作用下,在强偏析极限下研究了不对称AB二嵌段共聚物的微观相。我们评估了一组给定可能相的自由能,并给出了具有圆柱形本体相的二嵌段共聚物的相图,该相图取决于膜厚以及围壁与A或B单体之间的吸引力。这是针对不同的场强和体积分数完成的。我们发现,随着场强的增加,结构显示出与场对准的偏好。当少数单体的介电常数大于多数单体的介电常数时,取向更强。取决于壁电势的强度和膜厚度,壁可能会被少数单体完全润湿。 [http://dx.doi.org/10.1063/1.4738594]

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