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Colloidal rotation near the colloidal glass transition

机译:胶体玻璃化转变附近的胶体旋转

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摘要

We compare, using single-particle optical imaging, trajectories of rotation and translation for micron-sized spheres in index-matched colloidal suspensions near their glass transition. Rotational trajectories, while they show intermittent caged behavior associated with supercooled and glassy behavior, explore a sufficiently wider phase space such that in the averaged mean-square angular displacement there appears no plateau regime, but instead sub-Fickian angular diffusion that follows an apparent power law in time. We infer translation and rotation time constants, the former being the time to diffuse a particle diameter and the latter being the time to rotate a full revolution. Correlation between time constants increases with increasing volume fraction, but unlike the case for molecular glasses, the rotation time constant slows more weakly than the translation time.
机译:我们使用单粒子光学成像技术比较了折射率匹配的胶体悬浮液中接近玻璃化转变的微米级球体的旋转和平移轨迹。旋转轨迹虽然显示出与过冷和玻璃态行为相关的间歇性笼状行为,但探索了足够宽的相空间,使得在平均均方角位移中没有平稳状态,而是遵循了视力的次菲克角扩散法律及时。我们推断出平移和旋转时间常数,前者是扩散粒径的时间,后者是旋转一整圈的时间。时间常数之间的相关性随体积分数的增加而增加,但是与分子玻璃的情况不同,旋转时间常数比平移时间更慢地变慢。

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