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首页> 外文期刊>The Journal of Chemical Physics >The effect of correlated bath fluctuations on exciton transfer
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The effect of correlated bath fluctuations on exciton transfer

机译:相关浴液波动对激子传递的影响

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摘要

Excitation dynamics of various light harvesting systems have been investigated with many theoretical methods including various non-Markovian descriptions of dissipative quantum dynamics. It is typically assumed that each excited state is coupled to an independent thermal environment, i.e., that fluctuations in different environments are uncorrelated. Here the assumption is dropped and the effect of correlated bath fluctuations on excitation transfer is investigated. Using the hierarchy equations of motion for dissipative quantum dynamics it is shown for models of the B850 bacteriochlorophylls of LH_2 that correlated bath fluctuations have a significant effect on the LH_2 → LH_2 excitation transfer rate. It is also demonstrated that inclusion of static disorder is crucial for an accurate description of transfer dynamics.
机译:已经用许多理论方法研究了各种光收集系统的激发动力学,包括对耗散量子动力学的各种非马尔可夫描述。通常假设每个激发态都耦合到一个独立的热环境,即不同环境中的波动是不相关的。在此放弃了假设,并研究了相关浴槽波动对激励传递的影响。使用耗散量子动力学的运动层次方程,对于LH_2的B850细菌叶绿素模型,表明与浴液波动相关的LH_2→LH_2激发转移速率具有显着影响。还证明了包含静态障碍对于准确描述转移动力学至关重要。

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