Prevalence of approximate t relaxation for the dielectric process in viscous organic liquids

摘要

This paper presents dielectric relaxation data for organic glass-forming liquids compiled from different groups and supplemented by new measurements. The main quantity of interest is the “minimum slope” of the dielectric loss plotted as a function of frequency in a log-log plot, i.e.,the numerically largest slope above the loss peak frequency. The data consisting of 347 spectra for 53 liquids show prevalence of minimum slopes close to 1/2, corresponding to approximate t dependence of the dielectric relaxation function at short times. The paper studies possible correlations between minimum slopes and temperature quantified via the loss peak frequency;2 how well an inverse power-law fits data above the loss peak; 3 degree of time-temperature superposition; 4 loss peak half width; 5 deviation from non-Arrhenius behavior; 6 loss strength. For the first three points we find correlations that show a special status of liquids with minimum slopes close to 1/2. For the last three points only fairly insignificant correlations are found, with the exception of large-loss liquids that have minimum slopes that are numerically significantly larger than 1/2. We conclude that—excluding large-loss liquids—approximate t relaxation appears to be a generic property of the relaxation of organic glass formers.