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首页> 外文期刊>The Journal of Chemical Physics >Multidimensional spatial-spectral holographic interpretation of NMR photography
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Multidimensional spatial-spectral holographic interpretation of NMR photography

机译:NMR摄影的多维空间光谱全息解释

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摘要

A spectral holographic interpretation arises naturally in nuclear magnetic resonance (NMR) photography from either the intrinsic chemical shift anisotropy of the spin system or the field inhomogeneity due to the applied spatial encoding gradients.We can thus think of NMR photography as arising from a "diffraction" off a spatial-spectral holographic grating.The spatial holographic component arises from a high dielectric constant (>50) of the NMR medium at high field strength (>4 T) when the excitation wavelength is commensurate with the size of the NMR sample; otherwise,it is a volume spectral holographic grating.In this paper,the NMR localized spectroscopy (imaging) equation is derived from the principles of spatial-spectral holography.Holographic properties of storage and programmable time delay and time reversal are shown to follow naturally from this viewpoint and are experimentally demonstrated in an inhomogeneously broadened NMR sample.These ideas are shown to be extendable to complex signal processing functions such as recognition,correlations,and triple products.
机译:在核磁共振(NMR)摄影中,自旋系统的固有化学位移各向异性或由于施加的空间编码梯度导致的场不均匀性,自然会产生光谱全息解释。因此,我们可以认为NMR摄影是“衍射”引起的当激发波长与NMR样品的尺寸相称时,空间全息分量来自于在高场强(> 4 T)时NMR介质的高介电常数(> 50)。本文从空间光谱全息原理出发,推导了NMR局域光谱(成像)方程,表明了存储的全息性质以及可编程的时延和时间反转从这种观点已在不均匀扩展的NMR样品中得到了实验证明。这些思想可扩展到复杂的信号处理功能,例如识别,相关和三乘积。

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