Nonadiabatic transitions in the exit channel of atom-molecule collisions: Fine-structure branching in Na+N-2

摘要

We study Na+N-2 collisions by laser excitation of the collision complex in a differential scattering experiment. The measured relative population of the Na(3p) fine-structure levels reflects the nonadiabatic transitions occuring in the exit channel of the collision. Theoretical results obtained with a classical-path formalism and accurate quantum chemical data for NaN2 are found to be in good agreement. The presence of a conical intersection for the T-shaped geometry has a profound influence on the observed fine-structure branching.(C) 2004 American Institute of Physics.