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Controlled polymer dewetting by physical confinement

机译:通过物理限制来控制聚合物的去湿

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We report ordering of polymer drops that takes place when a thin polystyrene film confined by polydimethylsiloxane walls dewets on a silicon substrate. When annealed above the glass transition temperature, the thin polymer film dewets, resulting in the formation of a regular structure inside and outside the confinement. It is found that the ordering becomes strongly suppressed as the film thickness increases and the pattern size decreases due to the physical confinement of the mold. As a result, the ordering can take place only when the wavelength of the capillary wave is smaller than the characteristic length of the physical confinement.
机译:我们报道了由聚二甲基硅氧烷壁限制的聚苯乙烯薄膜在硅基材上润湿时发生的聚合物滴的排列。当在高于玻璃化转变温度的温度下退火时,聚合物薄膜会发生润湿,从而在封闭区域内外形成规则的结构。可以发现,由于模具的物理限制,随着膜厚度的增加和图案尺寸的减小,有序化被强烈抑制。结果,仅当毛细管波的波长小于物理限制的特征长度时才可以进行排序。

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