Spectral inhomogeneity induced by vacancies and thermal phonons and associated observables in time- and frequency-domain nonlinear spectroscopy: I_2 isolated in matrix argon

摘要

The vibrational self-consitent field method is used to analyze the inhomogeneous spectral distriubtion of transitions caused by vacancies and thermally populated phonons, specializing to molecular iodine isolated in an Ar matrix.