Synthesis of allylic sulfonic acids via regioselective Pd-catalyzed allylic substitutions of Na2SO3

Liu Wei; Zhao Xiaoming

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Synthesis of allylic sulfonic acids via regioselective Pd-catalyzed allylic substitutions of Na2SO3

机译：通过区域选择性Pd催化的Na2SO3烯丙基取代合成烯丙基磺酸

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Palladium-catalyzed allylic sulfonations of the linear allylic carbonates with sodium sulfite (Na2SO3) were accomplished under mild conditions. This method gave allylic sulfonic acids in good to excellent yields with high level of regioselectivities. (C) 2015 Elsevier Ltd. All rights reserved.

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2015年第48期|共3页
作者
Liu Wei; Zhao Xiaoming;
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正文语种 eng
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Regioselectivity; Allylation; Na2SO3; Palladium; Sulfonic acid;

机译：区域选择性;烯丙基化;Na2SO3;钯;磺酸;

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1. Synthesis of allylic sulfonic acids via regioselective Pd-catalyzed allylic substitutions of Na2SO3 [J] . Liu Wei, Zhao Xiaoming Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2015,第48期

机译：通过区域选择性Pd催化的Na2SO3烯丙基取代合成烯丙基磺酸
2. Stereoselective Synthesis of 1,4-Bifunctional Compounds by Regioselective Pd-Catalyzed Allylic Substitution Reaction [J] . Naoyoshi Maezaki, Yuki Hirose, Tetsuaki Tanaka Organic letters . 2004,第13期

机译：区域选择性Pd催化的烯丙基取代反应立体选择性合成1,4-双功能化合物
3. Pd-Catalyzed Three-Component Domino Reaction of Vinyl Benzoxazinanones for Regioselective and Stereoselective Synthesis of Allylic Sulfone-Containing Amino Acid Derivatives [J] . Hao Jiping, Xu Yi, Xu Zhongliang, Organic letters . 2018,第24期

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4. P-AMINO LIGANDS FROM IMINOSUGARS: NEW READILY AVAILABLE AND MODULAR LIGANDS FOR THE ASYMMETRIC PD-CATALYZED ALLYLIC SUBSTITUTION REACTION [C] . Inmaculada Robina, Carlota Borras, Pilar Ellas-Rodriguez International Carbohydrate Symposium . 2018

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5. Approaches to the total synthesis of (+/-)-pseudomonic acids. Model studies and reagent development in stereo- and regiocontrolled Pd-catalyzed alkylations and arylations of allylic alcohol derivatives. [D] . Brescia, Marc-Raleigh. 1997

机译：（+/-）-假单仲酸的全合成方法。立体和区域控制的Pd催化烯丙基醇衍生物的烷基化和芳基化的模型研究和试剂开发。
6. Regioselective molybdenum-catalyzed allylic substitution of tertiary allylic electrophiles: methodology development and applications [O] . Muhammad Salman, Yaoyao Xu, Shahid Khan, 2020

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7. New Versatile Pd-Catalyzed Alkylation of Indoles via Nucleophilic Allylic Substitution: Controlling the Regioselectivity [O] . -1

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Synthesis of allylic sulfonic acids via regioselective Pd-catalyzed allylic substitutions of Na2SO3

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