Regiospecific synthesis of cepanolide, a cancer chemoprotective micronutrient found in green onions

John Boukouvalas; Vincent Albert

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Regiospecific synthesis of cepanolide, a cancer chemoprotective micronutrient found in green onions

机译：ceepanolide的区域特异性合成，一种在大葱中发现的癌症化学保护微量营养素

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The naturally occurring γ-hydroxy-β-sulfanylbutenolide cepanolide and a range of new analogues were synthesized in concise, regiospecific manner through the combined use of 2-silyloxyfuran oxyfunctional-ization and tandem thio-Michael addition/elimination.

机译：通过结合使用2-甲硅烷基呋喃氧基官能化和串联硫代-迈克尔加成/消除反应，以简洁的区域特异性方式合成了天然存在的γ-羟基-β-硫烷基丁烯内酯环戊内酯和一系列新类似物。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2012年第24期|共3页
作者
John Boukouvalas; Vincent Albert;
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正文语种 eng
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Dimethyldioxirane; Butenolide; Furan; Organosulfur compound; Thio-Michael addition;

机译：二甲基二环氧乙烷;丁烯内酯;呋喃;有机硫化合物;硫-迈克尔加成;

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1. Regiospecific synthesis of cepanolide, a cancer chemoprotective micronutrient found in green onions [J] . John Boukouvalas, Vincent Albert Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2012,第24期

机译：ceepanolide的区域特异性合成，一种在大葱中发现的癌症化学保护微量营养素
2. REGIOSPECIFIC SYNTHESIS OF 3,4-DISUBSTITUTED FURANS .10. REGIOSPECIFIC SYNTHESIS OF 3,4-DISUBSTITUTED FURANS [J] . Song ZZ., Yang Y., Wong HNC. Pure and Applied Chemistry . 1996,第3期

机译：3,4-取代的呋喃的区域特异性合成.10。 3,4-二元取代呋喃的区域特异性合成
3. A new and green approach for regiospecific synthesis of novel chromeno-triazolopyrimidin using tungstic acid immobilized MCM-41 as a reusable catalyst [J] . Journal of Heterocyclic Chemistry: The International Journal of Heterocyclic Chemistry . 2020,第6期

机译：一种新的和绿色方法，用于使用钨酸固定化MCM-41作为可再用催化剂的新型铬苯甲唑吡啶蛋白
4. EFFECT OF BIOSTIMULANTS +/- MICRONUTRIENTS, HYDROXY-PROPANOIC ACID, CYTOKININS AND HUMIC ACID AS A TRANSPLANT DIP AND PLANT SPRAY ON ONIONS [C] . G. Boyhan, R. Torrance Annual Meeting of the Plant Growth Regulation Society of America . 2009

机译：生物阳离子+/-微量营养素，羟基 - 丙酸，细胞质素和腐殖酸作为移植浸渍和植物喷雾剂的影响
5. Identification of bioactive agents from green onion (Allium spp.) and organoselenium compounds with cancer chemopreventive potential. [D] . Xiao, Hang. 2004

机译：从具有癌症化学预防潜力的葱（葱属）和有机硒化合物中鉴定生物活性剂。
6. Templated green synthesis of plasmonic silver nanoparticles in onion epidermal cells suitable for surface-enhanced Raman and hyper-Raman scattering [O] . Marta Espina Palanco, Klaus Bo Mogensen, Marina Gühlke, 2016

机译：适用于表面增强拉曼和超拉曼散射的洋葱表皮细胞中等离激元银纳米粒子的模板绿色合成
7. Regiospecific synthesis by copper- and ruthenium-catalyzed azide–alkyne 1,3-dipolar cycloaddition, anticancer and anti-inflammatory activities of oleanolic acid triazole derivatives [O] . Chouaïb Karim, Romdhane Anis, Delemasure Stéphanie, 2016

机译：铜和钌催化的叠氮化物-炔烃1,3-偶极环加成反应的区域特异性合成，齐墩果酸三唑衍生物的抗癌和抗炎活性

Regiospecific synthesis of cepanolide, a cancer chemoprotective micronutrient found in green onions

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