A base-free, one-pot diazotization/cross-coupling of anilines with arylboronic acids

Fanyang Mo; Di Qiu; Yubo Jiang

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A base-free, one-pot diazotization/cross-coupling of anilines with arylboronic acids

机译：苯胺与芳基硼酸的无碱一锅重氮化/交叉偶联

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摘要

Pd-catalyzed one-pot diazotization/cross-coupling is realized for the synthesis of biaryls directly from anilines and arylboronic acids.

机译：实现了钯催化的一锅重氮化/交叉偶联，可直接从苯胺和芳基硼酸合成联芳基。

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来源
《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2011年第4期|共5页
作者
Fanyang Mo; Di Qiu; Yubo Jiang;
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正文语种 eng
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关键词
Pd-catalyzed; Suzuki-Miyaura coupling; Diazotization; Aryl amine;

机译：钯催化;铃木-宫浦偶联;重氮化;芳胺;

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专利

1. A base-free, one-pot diazotization/cross-coupling of anilines with arylboronic acids [J] . Fanyang Mo, Di Qiu, Yubo Jiang Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2011,第4期

机译：苯胺与芳基硼酸的无碱一锅重氮化/交叉偶联
2. Cu~(II)-β-cyclodextrin complex as a nanocatalyst for the homo-and cross-coupling of arylboronic acids under ligand-and base-free conditions in air: Chemoselective cross-coupling of arylboronic acids in water [J] . Kaboudin B., Abedi Y., Yokomatsu T. European journal of organic chemistry . 2011,第33期

机译：铜〜（II）-β-环糊精配合物作为纳米催化剂用于空气中无配体和无碱条件下芳基硼酸的均相和交叉偶联：水中芳基硼酸的化学选择性交叉偶联
3. Using Anilines as Masked Cross-Coupling Partners: Design of a Telescoped Three-Step Flow Diazotization, Iododediazotization, Cross-Coupling Process [J] . Teci Matthieu, Tilley Michael, McGuire Michael A., Chemistry: A European journal . 2016,第48期

机译：使用苯胺作为掩蔽的交叉偶联伙伴：伸缩三步流重氮化，碘化二重氮化，交叉偶联工艺的设计
4. The Suzuki-Miyaura cross-coupling of chloroarenes with arylboronic acids in supercritical carbon dioxide [C] . Ilya V. Kuchurov, Andrei A. Vasiliev, Sergei G. Zlotin European Meeting on Supercritical Fluids . 2010

机译：超临界二氧化碳中芳基硼酸氯酮的铃木 - 宫系交叉偶联
5. 1. Supramolecular extension of pi-conjugation in aniline oligomers. 2. Electroactive vesicle formations in amphiphilic block copolymer and aniline oligomer blends. 3. Collective carboxylic acid doping in aniline oligomers. [D] . Sai, Tsunehiro. 2006

机译：1.苯胺低聚物中π缀合的超分子延伸。 2.两亲嵌段共聚物和苯胺低聚物混合物中的电活性囊泡形成。 3.苯胺低聚物中的羧酸集体掺杂。
6. Direct One-Pot Synthesis of Primary 4-Amino-23-diaryl- quinolines via Suzuki-Miyaura Cross-Coupling of 2-Aryl-4-azido-3-iodoquinolines with Arylboronic Acids [O] . Malose Jack Mphahlele, Mamasegare Mabel Mphahlele 2011

机译：通过2-芳基-4-叠氮基-3-碘喹啉与芳基硼酸的铃木-宫浦交叉偶合直接一锅合成伯4-氨基-23-二芳基-喹啉
7. Phosphine ligand and base-free, Pd- catalyzed oxidative cross-coupling reaction of arylboronic acids with arylmercuric acetates [O] . Lourdusamy Emmanuvel, Arumugam Sudalai 2007

机译：膦配体和无碱，pd催化的芳基硼酸与芳基汞乙酸盐的氧化交叉偶联反应

A base-free, one-pot diazotization/cross-coupling of anilines with arylboronic acids

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