首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >A new sesquiterpenoid produced by female Callosobruchus rhodesianus (Pic): a possible component of the sex attractant pheromone
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A new sesquiterpenoid produced by female Callosobruchus rhodesianus (Pic): a possible component of the sex attractant pheromone

机译:雌性Callosobruchus rhodesianus(Pic)生产的一种新的倍半萜素:性诱剂信息素的可能成分

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摘要

(E)-6-Ethyl-2,10-dimethyl-5,9-undecadienaI was identified from female seed beetle, Callosobruchus rhodesianus (Pic), as an electroantennographic-detection (EAD) active compound in the male. The ratio of the (E)-6-ethyl-2,10-dimethyl-5,9-undecadienal and (3S,6E)-2,3-dihydrohomofarnesal, previously identified as a sex attractant pheromone, was estimated at approximately 1:4.5. In combination with the stereoiso-mer-activity relationship of 2,3-dihydrohomofarnesal, we suggest that this new compound might function as a minor sex attractant pheromone in C. rhodesianus.
机译:(E)-6-乙基-2,10-二甲基-5,9-十一碳二烯I是从雌性甲虫Rhodesianus(Pic)种子中鉴定出来的,作为雄性动物的电造影检测法(EAD)。 (E)-6-乙基-2,10-二甲基-5,9-十一碳二烯醛和(3S,6E)-2,3-二氢同型芳香醛的比例估计约为1: 4.5。结合2,3-二氢同功纤维的立体异构体-活性关系,我们建议这种新化合物可能在罗德氏梭菌中充当次要的性诱剂信息素。

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