A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines

Titz A; Radic Z; Schwardt O; Ernst B

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines

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A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines

机译：一种安全，方便的叠氮化三氟l的制备方法及其在重氮向伯胺的转移反应中的应用

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摘要

A safe and convenient method for the copper(II)-catalyzed diazo transfer from triflyl azide to primary amines is reported. By replacing CH2O2 by toluene the formation of hazardous side products, for example, azido-chloromethane and diazidomethane can be avoided. (c) 2006 Elsevier Ltd. All rights reserved.

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2006年第14期|共3页
作者
Titz A; Radic Z; Schwardt O; Ernst B;
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正文语种 eng
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关键词
SYNTHETIC METHODS; SODIUM-AZIDE; ALKYL AZIDES; EXPLOSION; REAGENT;

机译：合成方法;叠氮化钠;烷基叠氮化物;爆炸;反应;

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1. A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines [J] . Titz A, Radic Z, Schwardt O, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2006,第14期

机译：一种安全，方便的叠氮化三氟l的制备方法及其在重氮向伯胺的转移反应中的应用
2. One-pot preparation of methyl 2-diazo-3-oxopropionates comprising an aqueous 'sulfonyl-azide-free' (SAFE) diazo transfer step [J] . Zhmurov Petr A., Darin Dmitry V., Bakulina Olga Yu., Mendeleev Communications . 2020,第3期

机译：单罐制备甲基2-二氮杂-3-氧化酸盐，包含水性的“磺酰基 - 叠氮化物”（安全）双向转移步骤
3. An efficient and improved procedure for preparation of triflyl azide and application in catalytic diazotransfer reaction [J] . Ri-Bai Yan, Fan Yang, Yanfen Wu, Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2005,第52期

机译：一种高效，改进的叠氮化三氟噻吩制备方法及其在催化重氮转移反应中的应用
4. Catalytic Asymmetric Carbene Transfer Reaction of Diazo Oxime Ethers with Olefines [C] . Linh Da Ho, Kazutaka Shibatomi, Seiji Iwasa 日本化学会春季年会講演予稿集 . 2018

机译：二聚胺肟醚的催化不对称切菜转移反应烯烃
5. Phenyl Replacement Reactions: Solvent Effects on Reactions of Boroxines with Primary Amines [D] . Wilcox, Nicholas John 2015

机译：苯基取代反应：硼氧烷与伯胺反应的溶剂效应
6. Reaction of a nucleoside 2 4-dinitrophenyl phosphate with fluoride; a convenient method for the preparation of the nucleoside phosphorfluoridate. [O] . P W Johnson, R von Tigerstrom, M Smith 1975

机译：核苷24-二硝基苯基磷酸酯与氟化物的反应;一种方便的方法用于制备核苷磷酸酯。
7. Nonafluorobutanesulfonyl Azide: A Shelf-Stable Diazo Transfer Reagent for the Synthesis of Azides from Primary Amines [O] . Suárez, José Ramón, Trastoy, Beatriz, Pérez-Ojeda, M. Eugenia, 2010

机译：九氟丁烷磺酰基叠氮化物：一种稳定的重氮转移试剂，用于从伯胺合成叠氮化物
8. Reaction of Tris(cyclopentadienyl)uranium compounds with amines, azides, and related ligands. [R] . Rosen, R. K. 1989

机译：三（环戊二烯基）铀化合物与胺，叠氮化物和相关配体的反应。

A safe and convenient method for the preparation of triflyl azide, and its use in diazo transfer reactions to primary amines

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