An efficient synthesis of beta-amino esters via Zn(OTf)_2-catalyzed Mannich-type reaction

Wang-Ge Shou; Yun-Yun Yang; Yan-Guang Wang

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An efficient synthesis of beta-amino esters via Zn(OTf)_2-catalyzed Mannich-type reaction

机译：通过Zn（OTf）_2催化的曼尼希型反应有效合成β-氨基酯

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摘要

A Zn(OTf)_2-catalyzed Mannich-type reaction of the electron-deficient aromatic amines with the electron-deficient aro-matic aldehydes and diethyl malonic ester was described.This three-component reaction afforded the corresponding beta-amino esters in good yields.

机译：描述了锌（OTf）_2催化的缺电子芳香胺与缺电子的芳香醛和二乙基丙二酸酯的曼尼希型反应。此三组分反应可提供相应的β-氨基酯，收率高。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry 》 |2006年第11期| 共3页
作者
Wang-Ge Shou; Yun-Yun Yang; Yan-Guang Wang;
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1. An efficient synthesis of beta-amino esters via Zn(OTf)_2-catalyzed Mannich-type reaction [J] . Wang-Ge Shou, Yun-Yun Yang, Yan-Guang Wang Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2006 ,第11期

机译：通过Zn（OTf）_2催化的曼尼希型反应有效合成β-氨基酯
2. LiClO4-Accelerated Three-Component Mannich-Type Reaction of Diethyl Malonate with Imines: An Efficient Synthesis of beta-Amino Esters Under Solvent-Free Conditions [J] . Aryanasab F, Saidi MR Synthetic Communications . 2008 ,第22a24期

机译：丙二酸二乙酯与亚胺的LiClO4加速的三组分曼尼希型反应：无溶剂条件下高效合成β-氨基酯
3. LiClO4-Accelerated Three-Component Mannich-Type Reaction of Diethyl Malonate with Imines: An Efficient Synthesis of beta-Amino Esters Under Solvent-Free Conditions [J] . Aryanasab F, Saidi MR Synthetic Communications . 2008 ,第22期

机译：丙二酸二乙酯与亚胺的LiClO4加速三组分曼尼希型反应：无溶剂条件下β-氨基酯的高效合成
4. MESOPOROUS IRON ALUMINOPHOSPHATE: AN EFFICIENT CATALYST FOR ONE POT SYNTHESIS OF AMIDES BY ESTER-AMIDE EXCHANGE REACTION [C] . A.V. Vijayasankar, H. Kathyayini, Harikrishna Tumma, International Symposium on Inorganic Phosphate Materials : Phosphate Materials for Energy Storage . 2012

机译：中孔铁铝磷酸酯：通过酯 - 酰胺交换反应的一种罐合成酰胺的有效催化剂
5. Catalytic enantioselective synthesis of O-and N-substituted quaternary carbon stereogenic centers: 1. Aluminum-catalyzed alkylations of alpha-ketoesters with dialkylzinc reagents. 2. Silver-catalyzed vinylogous Mannich-type reactions of alpha-ketoimine esters with siloxyfurans [D] . Wieland, Laura Caroline 2008

机译：O和N取代的季碳立构中心的催化对映选择性合成：1.用二烷基锌试剂进行铝催化的α-酮酸酯的烷基化。 2.α-酮亚胺酯与甲硅烷氧基呋喃的银催化乙烯基曼尼希型反应
6. Pd(OAc)2-catalyzed domino reactions of 12-dihaloarenes and 2-haloaryl arenesulfonates with Grignard reagents: efficient synthesis of substituted fluorenes [O] . Cheng-Guo Dong, Qiao-Sheng Hu -1

机译：格氏试剂在Pd（OAc）2催化的12-二卤代芳烃和2-卤代芳基芳烃磺酸盐的多米诺反应：取代芴的有效合成
7. Efficient Synthesis of Maleimides and Carbazoles via Zn(OTf)2-Catalyzed Tandem Annulations of Isonitriles and Allenic Esters [O] . -1

机译：通过Zn（OTF）2催化的异腈和甲型酯的二氧化酰亚胺和咔唑的高效合成

An efficient synthesis of beta-amino esters via Zn(OTf)_2-catalyzed Mannich-type reaction

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