New modular P-chiral ligands for Rh-catalyzed asymmetric hydrogenation

Oleg G.Bondarev; Richard Goddard

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New modular P-chiral ligands for Rh-catalyzed asymmetric hydrogenation

机译：用于Rh催化不对称氢化的新型模块化P-手性配体

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摘要

New modular P-chiral ligands have been prepared from commercially available(S)-alpha,alpha-diphenylprolinol.With these new types of ligands,up to 95% ee was achieved in the Rh-catalyzed asymmetric hydrogenation of functionalized olefins.

机译：从市售的（S）-α，α-二苯基脯氨醇制备了新的模块化P-手性配体。有了这些新型的配体，在Rh催化的功能化烯烃的不对称加氢反应中，ee可达到95％。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2006年第51期|共3页
作者
Oleg G.Bondarev; Richard Goddard;
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正文语种 eng
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Asymmetric reactions; Phosphorus ligands; Rhodium; Hydrogenation.;

机译：不对称反应;磷配体;铑;加氢;

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专利

1. New modular P-chiral ligands for Rh-catalyzed asymmetric hydrogenation [J] . Oleg G.Bondarev, Richard Goddard Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2006,第51期

机译：用于Rh催化不对称氢化的新型模块化P-手性配体
2. Practical P-Chiral Phosphane Ligand for Rh-Catalyzed Asymmetric Hydrogenation [J] . Duan Liu, Xumu Zhang European journal of organic chemistry . 2005,第4期

机译：实用的P-手性磷配体用于Rh催化的不对称加氢
3. Modular P-chirogenic aminophosphane-phosphinite ligands for Rh-catalyzed asymmetric hydrogenation: A new model for prediction of enantioselectivity [J] . Darcel C, Moulin D, Henry JC, European journal of organic chemistry . 2007,第13期

机译：用于Rh催化不对称氢化的模块化P-手性氨基膦-次膦酸酯配体：预测对映选择性的新模型
4. P-Chiral Bidentate Phosphine Ligands for Catalytic Asymmetric Reactions [C] . Atsushi Kumada, Aya Koide, Youichi Saito Symposium on Organometallic Chemistry . 2007

机译：催化不对称反应的p-chiral二齿膦配体
5. Highly efficient asymmetric synthesis of novel diphosphine ligands with additional chiral centers on the backbone and their applications in asymmetric hydrogenation reactions. [D] . Qiu, Liqin. 2003

机译：在骨架上具有额外手性中心的新型二膦配体的高效不对称合成及其在不对称氢化反应中的应用。
6. Immobilization of Chiral Ferrocenyl Ligands on Silica Gel and their Testing in Pd-catalyzed Allylic Substitution and Rh-catalyzed Hydrogenation [O] . Ján Cvengroš, Štefan Toma, Mária Žembéryová, 2005

机译：手性二茂铁基配体在硅胶上的固定及其在Pd催化的烯丙基取代和Rh催化的加氢中的测试
7. Enantioselective Synthesis of b2-Amino Acids via Rh-Catalyzed Asymmetric Hydrogenation with BoPhoz-Type Ligands: Important Influence of an N-H Proton in the Ligand on the Enantioselectivity [O] . -1

机译：抗Bophoz型配体的Rh催化不对称氢化对B2-氨基酸的映选择性合成：N-H质子在配体对映选择性的重要影响

New modular P-chiral ligands for Rh-catalyzed asymmetric hydrogenation

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