Synthesis of the frist examples of p-bromodienone and transannular spirodienone calixarene derivatives.

Carmine Gaeta; Marco martino; Placido Neri

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Synthesis of the frist examples of p-bromodienone and transannular spirodienone calixarene derivatives.

机译：对溴代双烯酮和环戊螺二烯酮杯芳烃衍生物的第一个例子的合成。

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The first examples of p-bromodienone calixarene derivatives (6-7 and 9-10) have been obtained by treatment of 1,5-dihydroxy-hexaalkoxycalix[8] arenes 5 or tripropoxycalix[4]arene 8 with trimethylphenylammonium tribromide and a saturated solution of NaHCO_3.the first transannular spiriodienone derivative 11 was only obtained in the presence of NaOH or using the KOH/I_2/PEG-200 oxdizing system.

机译：通过用三溴化三甲基苯基铵和饱和溶液处理1,5-二羟基-六烷氧基杯[8]芳烃5或三丙杯[4]芳烃8，获得了对溴苯二茂酮杯芳烃衍生物的第一个实例（6-7和9-10）。仅在NaOH存在下或使用KOH / I_2 / PEG-200氧化系统获得第一环式螺二烯酮衍生物11。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2003年第51期|共5页
作者
Carmine Gaeta; Marco martino; Placido Neri;
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正文语种 eng
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calixarenes; oxidation; transannular spirodienone; p-bromodienone.;

机译：杯芳烃;氧化;环戊螺二烯酮;对溴莫烯酮;

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1. Synthesis of the frist examples of p-bromodienone and transannular spirodienone calixarene derivatives. [J] . Carmine Gaeta, Marco martino, Placido Neri Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2003,第51期

机译：对溴代双烯酮和环戊螺二烯酮杯芳烃衍生物的第一个例子的合成。
2. Synthesis of novel heterocyclic calixarenes via the Diels-Alder reaction of calix[4]bis(spirodienones) [J] . V B Ganga, E Suresh, C H Suresh Indian Journal of Chemistry, Section B. Organic Including Medicinal . 2008,第7期

机译：通过杯[4]双（螺二烯）的Diels-Alder反应合成新型杂环杯芳烃
3. SYNTHESIS AND REACTIONS OF LARGE-RING SPIRODIENONE CALIXARENE DERIVATIVES [J] . Grynszpan F., Biali SE., Aleksiuk O. Pure and Applied Chemistry . 1996,第6期

机译：大环螺啶酮杯芳烃衍生物的合成与反应
4. Development of molecular resists based on Phenyl4calixarene derivatives. [C] . Masatoshi Echigo, Hiromi Hayashi, Hiroaki Oizumi, Advances in Resist Materials and Processing Technology conference . 2010

机译：基于苯基的分子抗蚀剂的研制4钙酸甲烯衍生物。
5. Preliminary studies directed towards the design and synthesis of electro-active fluorene and calixarene derivatives. [D] . Abdelwahed, Sameh H. 2006

机译：初步研究涉及电活性芴和杯芳烃衍生物的设计和合成。
6. Transannular Diels-Alder/13-Dipolar Cycloaddition Cascade of 134-Oxadiazoles: Total Synthesis of a Unique Set of Vinblastine Analogues [O] . Erica L. Campbell, Colin K. Skepper, Kuppusamy Sankar, -1

机译：134-Oxadiazoles的跨环Diels-Alder / 13-偶极环加成级联：一套独特的长春碱类似物的全合成
7. A modified procedure for the synthesis of spirodienones from phenolic .ALPHA.-diazoketones. [O] . CHUZO IWATA, KAZUYUKI MIYASHITA, TOMOKO IMAO, 1985

机译：从酚醛肽素合成螺旋管的修饰过程。 - alpha.-Diazoketones。
8. New Examples of Clusters, Extended Metal-Metal Bonding and Interstitial Derivatives. [R] . Corbett, J. D. 1985

机译：集群，扩展金属 - 金属键合和间隙衍生物的新例子。

Synthesis of the frist examples of p-bromodienone and transannular spirodienone calixarene derivatives.

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