Novel method for the synthesis of #beta#-substituted #alpha#-haloenones by rhodium (II)-catalyzed reactions of diazodicarbonyl compounds with benzyl halides

Yong Rok Lee; Dae Hwan Kim

首页> 外文期刊>Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry >Novel method for the synthesis of #beta#-substituted #alpha#-haloenones by rhodium (II)-catalyzed reactions of diazodicarbonyl compounds with benzyl halides

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Novel method for the synthesis of #beta#-substituted #alpha#-haloenones by rhodium (II)-catalyzed reactions of diazodicarbonyl compounds with benzyl halides

机译：铑（II）催化重氮二羰基化合物与苄基卤化物反应合成＃beta＃取代的＃alpha＃-卤代烯酮的新方法

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The rhodium (II)-catalyzed reactions of diazodicarbonyl compounds with benzyl halides give #beta#-substituted #alpha#-haloenones in good yields.

机译：重氮二羰基化合物与苄基卤化物的铑（II）催化反应以高收率得到＃β＃取代的＃alpha＃-卤代烯酮。

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《Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry》 |2001年第37期|共3页
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Yong Rok Lee; Dae Hwan Kim;
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1. Novel method for the synthesis of #beta#-substituted #alpha#-haloenones by rhodium (II)-catalyzed reactions of diazodicarbonyl compounds with benzyl halides [J] . Yong Rok Lee, Dae Hwan Kim Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry . 2001,第37期

机译：铑（II）催化重氮二羰基化合物与苄基卤化物反应合成＃beta＃取代的＃alpha＃-卤代烯酮的新方法
2. Efficient synthesis of five- and seven-membered-ring heterocycles by rhodium(II)-catalyzed [3+2] and [3+4] cycloaddition of diazodicarbonyl compounds with conjugated dienes [J] . Lee YR, Hwang JC European journal of organic chemistry . 2005,第8期

机译：铑（II）催化重氮二羰基化合物与共轭二烯的[3 + 2]和[3 + 4]环加成反应，有效合成五元环和七元环杂环
3. Rhodium(II)-catalyzed dipolar cycloaddition of cyclic diazodicarbonyl compounds with alpha,beta-unsaturated esters. Synthesis of dihydrofurans [J] . Lee YR. Synthetic Communications . 1998,第5期

机译：铑（II）催化的环状重氮二羰基化合物与α，β-不饱和酯的偶极环加成反应。二氢呋喃的合成
4. Rhodium-catalyzed Synthesis of Unsymmetric Di(heteroaryl) Compounds Using Heteroaryl Exchange Reactions [C] . Mieko Arisawa 日本化学会春季年会講演予稿集 . 2018

机译：使用杂芳基交换反应的铑催化的非对称二（杂芳基）化合物的合成
5. Exploration of alpha-Diazocarbonyl Compounds for Transition-Metal Catalyzed Carbon-Carbon Bond Formations. Development of Palladium-Catalyzed Stereoselective Synthesis of Trisubstituted Alkenes and the Synthesis of Quaternary alpha,alpha-Heterodiaryl Carboxylic Acids by Rhodium-Catalyzed Multi-Component Coupling Reactions. [D] . Tsoi, Yuk Tai. 2012

机译：探索用于过渡金属催化的碳-碳键形成的α-重氮羰基化合物。铑催化的多组分偶合反应在钯催化的立体选择性合成三取代的烯烃上的发展和季铵的α，α-杂二芳基羧酸的合成。
6. Scope of the Reactions of Indolyl- and Pyrrolyl-tethered N-Sulfonyl-123-triazoles: Rhodium(II)-catalyzed Synthesis of Indole- and Pyrrole-fused Polycyclic Compounds [O] . Liangbing Fu, Huw M. L. Davies -1

机译：吲哚基和吡咯基束缚的N-磺酰基-123-三唑的反应范围：铑（II）催化的吲哚和吡咯稠合多环化合物的合成
7. Synthesis of 1Benzyl, 1Alkoxyl and 1Aminoisoquinolines via Rhodium(III)-Catalyzed Aryl CH Activation and Alkyne Annulation [O] . -1

机译：通过铑（III）的1苄基，1烷氧基和1氨基氨基喹啉的合成 - 催化芳基CH激活和炔烃环
8. Transfer Pd(0) Catalyzed Polymerization Reactions. III. Polymerization by Cross-Coupling of Alkyl-Boron Compounds and Aromatic Halides Catalyzed by PdCl2 (dppf) and Bases [R] . Cramer, E., Percec, V. 1990

机译：转移pd（0）催化的聚合反应。 III。 pdCl2（dppf）和碱催化的烷基硼化合物与芳香卤化物的交叉偶联聚合

Novel method for the synthesis of #beta#-substituted #alpha#-haloenones by rhodium (II)-catalyzed reactions of diazodicarbonyl compounds with benzyl halides

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