Role of molecular orbital symmetry on the alignment dependence of high-order harmonic generation with molecules - art. no. 061801

摘要

It is shown that the alignment dependence of the yields of high-order harmonic generation (HHG) from molecules by intense lasers is governed by the orbital symmetry of the outermost electron(s). For N-2, with its outermost sigma(g) electron, the HHG yield is maximal when the molecules are aligned with the laser polarization direction, in agreement with the recent experiment of Itatani [Nature 432, 867 (2004)]. For O-2, with its outermost pi(g) electron, the HHG yield peaks when the molecules are aligned at about 45 degrees from the polarization axis. We emphasize that the alignment dependence is determined mostly by the orbital symmetry and weakly on the laser parameters or the species.