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首页> 外文期刊>Physical Review, A. Atomic, molecular, and optical physics >High-order harmonic generation from two-center molecules: Time-profile analysis of nuclear contributions
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High-order harmonic generation from two-center molecules: Time-profile analysis of nuclear contributions

机译:从两个中心分子产生高次谐波:核贡献的时间曲线分析

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We solve the exact three-dimensional time-dependent Schrodinger equation for H-2(+) (with fixed nuclei) interacting with an intense laser pulse with an arbitrary oriented linear polarization. We find that at equilibrium internuclear distance, the ionization probability of H-2(+) is maximum for the parallel orientation of the molecule with respect to the laser polarization, and is minimum for the perpendicular orientation. The contribution of each nucleus to the harmonic spectrum is evaluated, so that interference effects between the two contributions are assessed unambiguously. We show that every half-cycle, high order harmonics are emitted by each nucleus when the electron wave packet returns for a recollision with both nuclei, and that the resulting harmonic emission is predominant for the nucleus that experiences the first recollision. In general, each nucleus emits both even and odd harmonics, but even harmonics are destroyed by interferences between contributions from each nucleus. In general, this destructive interference occurs over a large spread of harmonic orders, which depends on the angle between the molecular axis and the laser polarization.
机译:我们解决了H-2(+)(具有固定原子核)与具有任意取向的线性偏振的强激光脉冲相互作用时的精确三维时变Schrodinger方程。我们发现在平衡核间距下,H-2(+)的电离概率对于分子相对于激光偏振的平行方向最大,而对于垂直方向最小。评估每个原子核对谐波频谱的贡献,以便明确评估两个贡献之间的干扰效应。我们显示,当电子波包返回与两个原子核的碰撞时,每个原子核都会发射每个半周期的高次谐波,并且所产生的谐波发射对于经历第一次碰撞的原子核是主要的。通常,每个原子核都发射偶数和奇次谐波,但是偶数谐波会被每个原子核之间的干扰所破坏。通常,这种破坏性干涉发生在谐波阶数的大范围扩展上,这取决于分子轴和激光偏振之间的角度。

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