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Luminescence studies on gamma irradiated KCl: Ce ~3 crystals

机译:γ辐照的KCl:Ce〜3晶体的发光研究

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摘要

This paper reports thermoluminescence(TL), optical absorption and TL emission studies that are made on Ce ~3 doped KCl single crystals irradiated at room temperature. The glow curve and optical absorption studies indicate the participation of Ce ~3 ions in the TL process. The TL study suggests the presence of low concentration of Ce ~3 ions which reduces the TL efficiency with respect to pure KCl samples. On F bleaching γ irradiated crystals Z _1 centers are observed. A broader and strongly intense violet blue emission at 290, 370, 423 and 488 nm has been observed with 240 nm excitation. This emission has been attributed due to the transition from 5d(2D) excited energy level to the 4f ~1 ground stable energy level (2F _(5/2) and 3F _(7/2)) of Ce ~3 doped KCl crystals.
机译:本文报道了在室温下对Ce〜3掺杂的KCl单晶进行热致发光(TL),光吸收和TL发射的研究。辉光曲线和光吸收研究表明,Ce〜3离子参与了TL过程。 TL研究表明存在低浓度的Ce〜3离子,这相对于纯KCl样品降低了TL效率。在F漂白γ辐照的晶体Z _1中心。在240 nm激发下,观察到在290、370、423和488 nm处发出更宽且强烈的紫蓝光。这种发射归因于从Ce〜3掺杂的KCl晶体的5d(2D)激发能级到4f〜1地面稳定能级(2F _(5/2)和3F _(7/2))的转变。 。

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