Two Cd(II) coordination polymers based on asymmetrical Schiff-base ligand with five- and six-membered N-containing heterocyclic rings: Synthesis, crystal structures and luminescent properties

摘要

Two cadmium inorganic-organic hybrid coordination polymers [CdL(SCN)_2]_n (1) and [CdLI_2]_n (2), have been synthesized and characterized by IR spectroscopy, elemental analysis, XRPD, thermogravimetric (TG) analyses and X-ray crystallography, where L is 4-(pyridine-4-yl)methyleneamino-l,2,4-triazole. Asymmetrical Schiff-base ligand L acts as a bidentate bridging ligand to bind two Cd(II) centers through two terminal N_(triazolyl) and N_(pyridyl) donors in polymers 1 and 2. Polymer 1 displays a new 3D inorganic-organic hybrid network generated through the coordination interactions between Cd-(1,3-μ-SCN~-) 2D inorganic sheets and bidentate bridging ligands. The structure of polymer 2 is a 3D chiral supramolecular framework which contains helical chains on 2_1 axis. Each Cd(II) center is coordinated by two ligands and two I~- donors to attain a distorted tetrahedral environment. The luminescent properties of polymers 1 and 2 were investigated in the solid state at room temperature.