Synthesis, characterization and electroluminescence properties of iridium complexes based on pyridazine and phthalazine derivatives with CN=N structure

摘要

We reported the synthesis and characterization of three novel tris-cyclometalated iridium(III) complexes with pyridazine and phthalazine derivatives as ligands bearing CN=N structure, namely, Ir(PYA)_3, Ir(PHB)_3, and Ir(PHC)_3. Reactions of the ligands with IrCl_3-3H_2O directly afforded tris-cyclometalated iridium(III) complexes in 31-39% yields. X-ray analysis revealed that the complexes exhibited the facial configuration, and the Ir-C bond lengths of the complexes are 2.009(3), 2.013(3), 2.019(3) A for Ir(PYA)_3, and 1.993(4), 2.002(4), 2.004(4) A for Ir(PHB)_3, respectively. The iridium complexes-based OLEDs fabricated by spin-coating technique exhibited promising performance. At 4 wt% doping level and a practical luminance of 100 cd m~(-2), the external quantum efficiencies of the devices using Ir(PYA)_3, Ir(PHB)_3 and Ir(PHC)_3 as dopants reached 9.0, 6.9 and 9.3% photons/electron, respectively.