Mechanistic insight into direct arylations with ruthenium(II) carboxylate catalysts

Ackermann L.; Vicente R.; Potukuchi H.K.; Pirovano V.

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Mechanistic insight into direct arylations with ruthenium(II) carboxylate catalysts

机译：钌（II）羧酸盐催化剂直接芳基化的机理研究

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Mechanistic studies revealed ruthenium-catalyzed direct arylations to proceed through reversible C-H bond activation and subsequent rate-limiting oxidative addition with aryl halides, which led to the development of widely applicable well-defined ruthenium(II) carboxylate catalysts.

机译：机理研究表明，钌催化的直接芳基化反应通过可逆的C-H键活化作用以及随后与芳基卤化物的限速氧化加成反应来进行，这导致了广泛应用的定义明确的羧酸钌（II）催化剂的发展。

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《Organic letters》 |2010年第21期|共4页
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Ackermann L.; Vicente R.; Potukuchi H.K.; Pirovano V.;
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1. Mechanistic insight into direct arylations with ruthenium(II) carboxylate catalysts [J] . Ackermann L., Vicente R., Potukuchi H.K., Organic letters . 2010,第21期

机译：钌（II）羧酸盐催化剂直接芳基化的机理研究
2. Dehydrative C-H/N-OH Functionalizations in H2O by Ruthenium(II) Catalysis: Subtle Effect of Carboxylate Ligands and Mechanistic Insight [J] . Yang Fanzhi, Ackermann Lutz The Journal of Organic Chemistry . 2014,第24期

机译：钌（II）催化H2O中的脱水C-H / N-OH官能化：羧酸盐配体的细微作用和机理研究
3. Direct CH bond Arylation in Water Promoted by (O,O)- and (O,N)-Chelate Ruthenium(II) Catalysts [J] . ChemCatChem . 2013,第6期

机译：通过（O，O） - 和（O，N） - 水钌（II）催化剂促进的水中的直接CH键芳基化促进
4. Development of In Situ Generated Ruthenium Phosphine Catalysts for Selective Arylation of Aromatic Compounds via C–O Bond Cleavage and Asymmetric Synthesis [C] . Hikaru Kondo, Takuya Kochi, Fumitoshi Kakiuchi 日本化学会春季年会講演予稿集 . 2018

机译：原位生成的钌膦催化剂的发展，用于通过C-O键切割和不对称合成选择性芳族化合物的选择性芳族化
5. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

机译：I.多催化作用：在复杂的杂环化合物的合成中三氟甲磺酸铋（III）催化的亲核加成/加氢官能化反应的发展。羰基钯催化剂对芳烃和杂芳烃的CH-H芳基化反应：催化剂静止状态的鉴定以及新戊酸酯配体在稳定催化剂中的关键作用III。羰基钯催化剂催化杂芳烃的CH芳基化：膦配体对基础杂芳烃基质的重要性IV。杂芳烃与钯-羧酸酯的CH芳基化：碱性杂芳烃底物性能对直接芳基化的影响。
6. Mechanistic Investigations and Substrate Scope Evaluationof Ruthenium-Catalyzed Direct sp3 Arylation of BenzylicPositions Directed by 3-Substituted Pyridines [O] . Navid Dastbaravardeh, Karl Kirchner, Michael Schnürch, -1

机译：机械调查和基板范围评估钌催化的sp3直接苯甲酰化反应由3取代的吡啶指示的位置
7. Direct Arylation of Arene C-H Bonds by Cooperative Action of NHCarbene-Ruthenium(II) Catalyst and Carbonate via Proton Abstraction Mechanism [O] . -1

机译：通过质子抽象机制通过Nhcarbene-钌（II）催化剂和碳酸酯的合作作用直接芳烃C-H键的粘结

Mechanistic insight into direct arylations with ruthenium(II) carboxylate catalysts

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