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Tuning the properties of cobalt ferrite: a road towards diverse applications

机译:调整钴铁氧体的特性:通往多样化应用的道路

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摘要

Cobalt ferrite has gained great scientific interest because of its unique properties and exceptionally promising applications. A large number of synthetic methods, such as sol-gel auto-combustion method, co-precipitation method, ball milling method, microemulsion method, polyol method, etc. have been used for its synthesis. Synthetic methodologies and heat treatment given to the sample strongly influence the particle size of the synthesized ferrite, which in turn determines its properties. In addition, the properties of cobalt ferrite can be altered by different chemical modifications such as substituting one or more ions from the lattice with some other metal ion, modifying the reaction conditions, compositing with different inorganic matrices etc. The most prominent influence on the properties of ferrites is exerted by variation in cation distribution. Among all the factors the major influence on the cation distribution is laid by doping. Guest metal ions according to their site preference occupy different lattice sites, thereby, changing the structural, magnetic, electrical and the catalytic properties of cobalt ferrite. In this review, we summarize the significant developments involving modifications in synthesis and properties of cobalt ferrite. This review also highlights the advances in the applications of cobalt ferrite in the fields of catalysis, biomedicine and sensors.
机译:铁氧体钴因其独特的性能和非常有前途的应用而获得了极大的科学兴趣。溶胶-凝胶自燃法,共沉淀法,球磨法,微乳液法,多元醇法等大量合成方法已被用于合成。样品的合成方法和热处理会严重影响合成铁氧体的粒径,进而决定其性能。另外,可通过不同的化学修饰来改变钴铁氧体的性能,例如用某种其他金属离子取代晶格中的一个或多个离子,改变反应条件,与不同的无机基质复合等。对性能的影响最为显着。铁氧体的分布是由于阳离子分布的变化而产生的。在所有因素中,掺杂对阳离子分布的主要影响。客体金属离子根据其位置偏好占据不同的晶格位置,从而改变了钴铁氧体的结构,磁性,电学和催化性能。在这篇综述中,我们总结了涉及钴铁氧体合成和性能改性的重大进展。这篇综述还强调了钴铁氧体在催化,生物医学和传感器领域的应用进展。

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