Evolution of Gel Structure during Thermal Processing of Na-Geopolymer Gels

摘要

The present work examines how the gel structure and phase composition of Na-geopolymers derived from metakaolin with varied Si/Al ratio evolve with exposure to temperatures up to 1000 deg C.Gels were thermally treated and characterized using quantitative XRD,DTA,and FTIR to elucidate the changes in gel structure,phase composition,and porosity at each stage of heating.It is found that the phase stability,defined by the amount and onset temperature of crystallization,is improved at higher Si/Al ratios.Two different mechanisms of densification have been isolated by FTIR,related to viscous flow and collapse of the highly distributed pore network in the gel.Gels with low Si/Al ratio only experience viscous flow that correlates with low thermal shrinkage.Gels at a higher Si/Al ratio,which have a homogeneous microstructure composed of a highly distributed porosity,undergo both densification processes corresponding to a large extent of thermal shrinkage during densification.This work elucidates the intimate relationship between gel microstructure,chemistry,and thermal evolution of Na-geopolymer gels.