Functional microspheres of graphene quantum dots

摘要

Graphene-quantum-dot microspheres (GQDSs) have been prepared by assembly of graphene quantum dots (GQDs) via a water-in-oil (W/O) emulsion technique without the addition of any surfactants. Although made of quantum-sized graphene dots, the as-formed GQDSs are solid and remain intact after slight ultrasonication. The versatile W/O emulsion method allows the insitu intercalation of functional nanocomponents into the GQDSs for specific applications. As exemplified by the Fe _3O _4-containing GQDSs, Fe _3O _4GQDSs exhibit a large magnetic response. Furthermore, the embedded Fe _3O _4 nanoparticles in GQDSs can act as the catalysts for the growth of carbon nanotubes (CNTs), which opens the opportunities for fabricating new complex structures of CNTs surrounding GQDSs by simple chemical vapor deposition.