StructureandMorphologyinHighlyOrientedFilmsofPoly(9,9-bis(n-octyl)fluorene-2,7-diyl)andPoly(9,9-bis(2-ethylhexyl)fluorene-2,7-diyl)GrownonFrictionTransferredPoly(tetrafluoroethylene)

MartinBrinkmann; NipaphatCharoenthai; RakchartTraiphol; PhimwiphaPiyakulawat; JoergWlosnewski; UdomAsawapirom

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StructureandMorphologyinHighlyOrientedFilmsofPoly(9,9-bis(n-octyl)fluorene-2,7-diyl)andPoly(9,9-bis(2-ethylhexyl)fluorene-2,7-diyl)GrownonFrictionTransferredPoly(tetrafluoroethylene)

机译：聚（9,9-双（正辛基）芴-2,7-二基）和聚（9,9-双（2-乙基己基）芴-2,7-二基）高取向薄膜的高取向膜的结构和形态学

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Thisstudyfocusesontheepitaxialorientationoftwopolyfluorenes(PF)namelypoly-(9,9-bis(n-octyl)fluorene-2,7-diyl)(PFO)andpoly(9,9-bis(2-ethylhexyl)fluorene-2,7-diyl)(PF2/6)onfrictiontransferredpoly(tetrafluoroethylene).PF2/6filmswithasingle-crystallikeorientationareobtainedonPTFEsubstratesafterproperannealingwhereasonlymarginalorientationisobservedforPFOfilms.Forbothpolymers,thecrystallinelamellaegrowessentiallyperpendiculartothePTFEchaindirectionandtheepitaxialconditionsweredeterminedas[001]PF//[001]PTFEand(010)PF//(100)PTFE.ForPF2/6sampleswithdifferentmolecularweightdistributions,thelamellarthicknesstendstoincreasewithincreasingaveragemolecularweightofthepolymer.Thecloseexaminationoftheselectedareaelectrondiffraction(SAED)patternscorrespondingtothe[010]PF26zonesupportsa214helicalconformationofthePF2/6chains.AsimplestructuralmodelbasedonatrigonalcellwithP3spacegroup,a=b=1.68nmandc=16.9nmcontainingatripletof214helicesaccountswellforthemainfeaturesoftheobservedelectrondiffractionpattern.Thethree214helicesofthetripletshowperiodicshortcontactseveryfifthmonomeralongthehelixaxis,suggestingthatthesupramolecularassemblyofthePF2/6chainsformingthetripletisstabilizedbyefficientπ-stackingbetweenfluorenemonomers.TheobserveddifferenceinorientationofPF2/6andPFOonPTFEsubstratessupportsanorientationmechanisminvolvingthePTFEmacrosteps.

机译：本研究的重点是两个聚芴（PF）的外延取向，即聚-（9,9-双（正辛基）芴-2,7-二基）（PFO）和聚（9,9-双（2-乙基己基）芴-2,7-二基）（PF2） /6)onfrictiontransferredpoly(tetrafluoroethylene).PF2/6filmswithasingle-crystallikeorientationareobtainedonPTFEsubstratesafterproperannealingwhereasonlymarginalorientationisobservedforPFOfilms.Forbothpolymers,thecrystallinelamellaegrowessentiallyperpendiculartothePTFEchaindirectionandtheepitaxialconditionsweredeterminedas[001]PF // [001] PTFEand（010）PF //（100）PTFE.ForPF2 / 6sampleswithdifferentmolecularweightdistributions，thelamellarthicknesstendstoincreasewithincreasingaveragemolecularweightofthepolymer.Thecloseexaminationoftheselectedareaelectrondiffraction（SAED）patternscorrespondingtothe [ 010] PF26zone支持PF2 / 6链的214螺旋形构形。一个基于结构的模型，带有P3空间群的三角形单元，a = b = 1.68nm和c = 16.9nm，包含一个由214个螺旋组成的三重形，可以看出主要特征是软的可观察到的电子衍射图样。三个214螺旋软四边形在螺旋轴上每隔五个单体就出现短周期接触，这表明形成三重膜的PF2 / 6链的超分子组装可通过芴单体之间的有效π堆积而稳定下来。

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《Macromolecules》 |2009年第21期|共9页
作者
MartinBrinkmann; NipaphatCharoenthai; RakchartTraiphol; PhimwiphaPiyakulawat; JoergWlosnewski; UdomAsawapirom;
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orientation; weight; conditions;

机译：方向;重量;条件;

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1. StructureandMorphologyinHighlyOrientedFilmsofPoly(9,9-bis(n-octyl)fluorene-2,7-diyl)andPoly(9,9-bis(2-ethylhexyl)fluorene-2,7-diyl)GrownonFrictionTransferredPoly(tetrafluoroethylene) [J] . MartinBrinkmann, NipaphatCharoenthai, RakchartTraiphol, Macromolecules . 2009,第21期

机译：聚（9,9-双（正辛基）芴-2,7-二基）和聚（9,9-双（2-乙基己基）芴-2,7-二基）高取向薄膜的高取向膜的结构和形态学
2. Self-Assembly of Poly{1,4-phenylene-[9,9-bis(4-phenoxy-butylsulfonate)]fluorene-2,7-diyl} with Oppositely Charged Phenylenevinylene Oligoelectrolytes [J] . Telma Costa, Ana T. Marques, J. Sergio Seixas de Melo The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical . 2014,第2期

机译：聚{1,4-亚苯基-[9,9-双（4-苯氧基-丁基磺酸盐）]芴-2,7-二基}与带正电荷的苯撑乙烯撑低聚物的自组装
3. Singlet Excitation Energy Harvesting And Triplet Emission In The Self-assembled System Poly{1 ,4-phenylene-[9,9-bis(4-phenoxy-butylsulfonate)]fluorene-2,7-diyl} Copolymer/tris(bipyridyl)ruthenium(ii)rnin Aqueous Solution [J] . Hugh D. Burrows, Sofia M. Fonseca, Fernando B. Dias, Advanced Materials . 2009,第10a11期

机译：自组装体系聚{1,4-亚苯基-[9,9-双（4-苯氧基-丁基磺酸盐）]芴-2,7-二基}共聚物/三（联吡啶）钌的单重态激发能收集和三重态发射（ii）rnin水溶液
4. Photoluminescence Study Of Poly (9,9-Di-N-Octylfluorenyl-2,7-Diyl)/Flourol 7GA/Poly2-Methoxy-5-(2-Ethylhexyloxy)-1,4-Phenylenevinylene Blends [C] . Siti Aishah Ahmad Fuzi, Mohammad Hafizuddin Hj Jumali, Bandar Ali Al-Asbahi International Workshop on Nanotechnology for Young Scientists . 2017

机译：聚（9,9-二 - 辛基氟烯基-2,7-二基）/番醇7GA /聚2-甲氧基-5-（2-乙基己氧基）-1,4-苯乙烯共混物的光致发光研究
5. Morphological Effects on Spin-Dependent Electronic Processes in Poly[9,9-Dioctylfluorenyl-2,7-Diyl] Thin Film Organic Light Emitting Diodes. [D] . Miller, Richards G., III. 2017

机译：聚[9,9-二辛基芴基-2,7-二基]薄膜有机发光二极管中自旋相关电子过程的形态学影响。
6. rac-7,7′,9,9′-Tetraphenyl-9a,9a′-bi(7,8,9,9a-tetrahydro-6aH-pentaleno[1,2,3-ij]naphthalen-8-one) [O] . Xiangdong Zhang, Junwei Ye, Weitao Gong, 2015

机译：rac-7,7'，9,9'-四苯基-9a，9a'-bi（7,8,9,9a-四氢-6aH-五leno [1,2,3-ij]萘-8-一）
7. X-ray Diffraction Studies of Multiple Orientation in Poly(9,9-bis(2-ethylhexyl)fluorene-2,7-diyl) Thin Films [O] . Knaapila, Matti, Lyons, Benjamin P., Monkman, Andrew P., 2003

机译：聚（9,9-双（2-乙基己基）芴-2,7-二基）薄膜中多个取向的X射线衍射研究

StructureandMorphologyinHighlyOrientedFilmsofPoly(9,9-bis(n-octyl)fluorene-2,7-diyl)andPoly(9,9-bis(2-ethylhexyl)fluorene-2,7-diyl)GrownonFrictionTransferredPoly(tetrafluoroethylene)

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