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Effectiveness of some non ionic surfactants as corrosion inhibitors for carbon steel pipelines in oil fields

机译:某些非离子表面活性剂在油田碳钢管道中作为缓蚀剂的功效

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The ability of new synthesized non ionic surfactants (I and II) to protect carbon steel in acid chloride solution was investigated using potentiostatic polarization, open circuit potential, weight loss and surface tension measurements. The experimental results showed that these inhibitors revealed a very good corrosion inhibition even at low concentrations. The percentage inhibition efficiency (η%) increases by increasing the inhibitor concentration until the critical micelle concentration (cmc) is reached. It was found that, the adsorption ability of the surfactant molecules on carbon steel surface increased with the increase of the molecular size of the surfactant. Potentiostatic polarization curves indicate that the inhibitors under investigation act as mixed type. Finally, the mechanism of carbon steel dissolution in acidic medium was discussed both in absence and presence of the inhibitor molecules.
机译:使用恒电位极化,开路电势,重量损失和表面张力测量,研究了新合成的非离子表面活性剂(I和II)在酰氯溶液中保护碳钢的能力。实验结果表明,即使在低浓度下,这些抑制剂也显示出很好的腐蚀抑制作用。通过增加抑制剂的浓度直至达到临界胶束浓度(cmc),抑制效率百分比(η%)会增加。发现,表面活性剂分子在碳钢表面上的吸附能力随着表面活性剂分子尺寸的增加而增加。恒电位极化曲线表明所研究的抑制剂为混合型。最后,讨论了在不存在和存在抑制剂分子的情况下碳钢在酸性介质中的溶解机理。

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