Stabilization of electric arc furnace dust by the use of cementitious materials: Ionic competition and long-term leachability

摘要

Ionic competition in stabilization of major heavy metals from electric arc furnace dust (EAFD) was investigated. The cementitious materials tested (ground granulated blast furnace slag (GGBFS) and ordinary Portland cement (OPC)) were put in contact with solutions made of various combinations of Cr(VI), Pb(II), Zn(II), Ni(II) and Mo(VI) ions. The presence of Ni, Zn or Mo did not influence the Cr fixation by GGBFS and OPC. The ionic competition phenomenon between Cr and Pb was observed for GGBFS in particular. Long-term leaching tests with OPC-EAFD and GGBFS-EAFD showed that OPC is more effective in fixing Cr at 7 days (4.7 mg/L in solution) than GGBFS (79.4 mg/L in solution). GGBFS becomes effective with time and offers a better performance from 56 to 365 days (under 1 mg/L in solution) than OPC (until 11 mg/L in solution). GGBFS and OPC decreased Zn, Pb and Ni concentrations in leaching solutions under 2.5 mg/L.