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Field experiences in concrete deterioration by thaumasite formation: possibilities and problems in thaumasite analysis

机译:高岭土形成引起混凝土劣化的现场经验:高岭土分析的可能性和问题

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摘要

In Germany, after testing two concretes deteriorated due to the formation of thaumasite, possibilities and problems in analysing thaumasite and ettringite-containing concrete samples will be discussed. The image of polished thin sections show, that thaumasite formation leads to microstructures similar to the microstructure of ettringite. It is recognisable in the microstructure that the formation of thaumasite happens as well via deterioration of CSH-phases as via the decomposition of ettringite. The identification of thaumasite using environmental scanning electron microscopy is possible without problems. Investigations using X-ray powder diffraction did show, that quantitative analysis of thaumasite and ettringite is possible by using the Rietveld method. The samples of deteriorated concrete (excluding coarse aggregate) contain 20-75 percent thaumasite.
机译:在德国,在测试了两种由于高岭石形成而劣化的混凝土之后,将讨论分析高岭石和含钙矾石的混凝土样品的可能性和问题。抛光的薄切片的图像显示,硅藻土的形成导致类似于钙矾石的微观结构的微观结构。在微观结构中可以认识到,通过CSH相的劣化以及钙矾石的分解也发生了硅藻土的形成。使用环境扫描电子显微镜鉴定Thaumasite可能没有问题。使用X射线粉末衍射进行的研究确实表明,使用Rietveld方法可以定量分析taumasite和钙矾石。劣化混凝土(不包括粗骨料)的样品中包含20-75%的硅藻土。

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