Aggregation and catalytic properties of polymer-calix[4]resorcinarene-water-dimethylformamide systems

Pashirova TN; Lukashenko SS; Kosacheva EM; Leonova MV; Knyazeva IR; Burilov AR; Kudryavtseva LA; Konovalov AI

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Aggregation and catalytic properties of polymer-calix[4]resorcinarene-water-dimethylformamide systems

机译：聚合物杯[4]间苯二芳烃-水-二甲基甲酰胺体系的聚集和催化性能

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The aggregation in poly(ethylene imine) (poly(ethylene glycol))-calix[4]resorcinarene-water-dimethylformamide (30 vol %) systems and the catalytic activity of these compositions in hydrolysis of 4-nitrophenylbis(chloromethyl)phosphinate are studied by conductometry, tensiometry, lightscattering, and viscometry. Critical association concentrations, hydrodynamic radii of polymer-colloid aggregates, and kinetic parameters of hydrolysis are determined.

机译：研究了聚（亚乙基亚胺）（聚（乙二醇））-杯[4]间苯二芳烃-水-二甲基甲酰胺（30体积％）体系中的聚集以及这些组合物在4-硝基苯基双（氯甲基）次膦酸酯水解中的催化活性。通过电导测定法，张力测定法，光散射法和粘度测定法。确定了临界缔合浓度，聚合物-胶体聚集体的流体力学半径和水解动力学参数。

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来源
《Colloid journal》 |2008年第2期|共8页
作者
Pashirova TN; Lukashenko SS; Kosacheva EM; Leonova MV; Knyazeva IR; Burilov AR; Kudryavtseva LA; Konovalov AI;
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原文格式 PDF
正文语种 eng
中图分类胶体;
关键词
OIL MICROEMULSIONS; HYDROLYSIS;

机译：油微乳液;水解;

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1. Aggregation and catalytic properties of polymer-calix[4]resorcinarene-water-dimethylformamide systems [J] . Pashirova TN, Lukashenko SS, Kosacheva EM, Colloid journal . 2008,第2期

机译：聚合物杯[4]间苯二芳烃-水-二甲基甲酰胺体系的聚集和催化性能
2. Systems based on nonionic amphiphilic compounds: aggregation and catalytic properties [J] . Yu. R. Ablakova, A. B. Mirgorodskaya, L. Ya. Zakharova Russian Chemical Bulletin . 2010,第4期

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3. Aggregation Behavior and Catalytic Properties of Systems Based on Aminomethylated Calix[4]resorcinarenes and Poly (ethylene) Imines [J] . T. N. Pashirova, S. S. Lukashenko, E. M. Kosacheva Russian Journal of General Chemistry . 2008,第3期

机译：氨基甲基化杯[4]间苯二芳烃和聚乙烯亚胺的体系的聚集行为和催化性能
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Aggregation and catalytic properties of polymer-calix[4]resorcinarene-water-dimethylformamide systems

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