Bis- and tris-chelates of Ni~(II), Cu~(II), Co~(II) and Fe~(III) bound to N,N-dialkyl/alkyl aryl-N'-benzoylthiourea ligands

摘要

Bis- and tris-chelates (1-5) of Ni(II), Cu(II), Fe(III) and Co(II) with two O,S donor substituted benzoylthiourea based ligands 3,3-diethyl-1-benzoylthiourea (HL~1) and 3-methyl-3-phenyl-1-benzoylthiourea (HL~2) have been synthesized and structurally characterized by X-ray crystallography. The keto-thione form of the free ligands transform to the keto-thiol form during coordination through neutral O and anionic S atoms. Crystallographic characterizations with supportive spectroscopic signatures confirm the cis-conformation in bis-chelates and facial binding to the tris-chelates.