Reactivity towards dixygen of copper (I) complex of tris(2-benzylaminoethyl) amine

Markus Schatz; Michael Beacker; Olaf Walter; Gunter Liehr; fSiegfried Schindler

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Reactivity towards dixygen of copper (I) complex of tris(2-benzylaminoethyl) amine

机译：三（2-苄基氨基乙基）胺的铜（I）配合物对二氧键的反应性

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The reaction of dioxygen with the copper (I) Bz_3tren complex (Bz_3tren=tris(2-benzylaminoethy)amine) complex has been investigated using low temperature stopped-flow techniques. The formations of a superoxo as well a superoxo complex as intermediates was detected spectroscopically . The copper (III) complexes [Cu(Bz_3tren)H_2O(ClO_4)_2] and [Cu(Bz_3tren)(Cl)]Cl were synthesized and structurally characterized. Both complexes react with dioxygen in solutions and formation of benzaldehyde was observed

机译：已经使用低温停止流技术研究了双氧与铜（I）Bz_3tren络合物（Bz_3tren =三（2-苄基氨基乙基）胺）的反应。用光谱法检测到了一种超级氧以及一个超级氧配合物的形成。合成了铜（III）配合物[Cu（Bz_3tren）H_2O（ClO_4）_2]和[Cu（Bz_3tren）（Cl）] Cl。两种络合物均与溶液中的双氧反应并观察到苯甲醛的形成

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《Inorganica Chimica Acta》 |2001年第2期|共7页
作者
Markus Schatz; Michael Beacker; Olaf Walter; Gunter Liehr; fSiegfried Schindler;
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正文语种 eng
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copper complexes; tripodal ligands; dioxygen activation; peroxo/superoxo complexes;

机译：铜配合物;三脚架配体;双氧活化;过氧/超氧配合物;

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1. Reactivity towards dixygen of copper (I) complex of tris(2-benzylaminoethyl) amine [J] . Markus Schatz, Michael Beacker, Olaf Walter, Inorganica Chimica Acta . 2001,第1a2期

机译：三（2-苄基氨基乙基）胺的铜（I）配合物对二氧键的反应性
2. Solution studies of tris(2-benzylaminoethyl)amine complexes of zinc(II) and copper(II): The catalytic hydrolysis of toxic organophosphate [J] . Gaber A.M. Mersal, Mohamed M. Ibrahim Comptes Rendus Chimie . 2012,第4期

机译：锌（II）和铜（II）的三（2-苄氨基乙基）胺配合物的溶液研究：有毒有机磷酸酯的催化水解
3. H2O2-Reactivity of Copper(II) Complexes Supported by Tris[(pyridin-2-yl)methyl]amine Ligands with 6-Phenyl Substituents [J] . Kunishita A, Kubo M, Ishimaru H, Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics . 2008,第24期

机译：三[（吡啶-2-基）甲基]胺配体与6-苯基取代基负载的铜（II）配合物的H2O2-反应活性
4. Synthesis of Metal Complexes with Tris(oxazolinylmethyl)amine Ligand and Their Catalytic Activity for Alkane Oxidation [C] . Jun Nakazawa, Junpei Endo, Naoki Jyozawa 日本化学会春季年会講演予稿集 . 2018

机译：三（恶唑啉基甲基）胺配体合成金属配合物及其烷烃氧化催化活性
5. Synthesis and reactivity of tungsten tris-(tri-tertbutyl) silyl imido complexes: Neutral and anionic derivatives, indirect evidence for the intermediacy of metal-alkane complexes in solution [D] . Schafer, Daniel Francis, II 1999

机译：钨三-（三叔丁基）甲硅烷基亚氨基配合物的合成和反应性：中性和阴离子衍生物，溶液中金属-烷烃配合物的间接证据
6. Synthesis of Two Potentially Heptadentate (N4O3) Schiff-base Ligands Derived from Condensation of Tris(3-aminopropyl)-amine and Salicylaldehyde or 4-Hydroxysalicylaldehyde. Nickel(II) and Copper(II) Complexes of the Former Ligand. [O] . Hassan Keypour, Sadegh Salehzadeh, R. V. Parish 2002

机译：三（3-氨基丙基）-胺与水杨醛或4-羟基水杨醛缩合衍生的两种潜在的七齿（N4O3）Schiff碱配体的合成。前配体的镍（II）和铜（II）配合物。
7. Synthesis, structural characterization, reactivity, and catalytic properties of copper(I) complexes with a series of tetradentate tripodal tris(pyrazolylmethyl)amine ligands [O] . Haldón Estela, Delgado-Rebollo M., Prieto María Auxiliadora, 2014

机译：具有一系列四齿三脚架三（吡唑基甲基）胺配体的铜（I）配合物的合成，结构表征，反应性和催化性能

Reactivity towards dixygen of copper (I) complex of tris(2-benzylaminoethyl) amine

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