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首页> 外文期刊>Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics >From 1D to 3D single-crystal-to-single-crystal structural transformations based on linear polyanion [Mn_4(H_2O)_(18)WZnMn _2(H_2O)_2(ZnW_9O_(34)) _2]~(4-)
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From 1D to 3D single-crystal-to-single-crystal structural transformations based on linear polyanion [Mn_4(H_2O)_(18)WZnMn _2(H_2O)_2(ZnW_9O_(34)) _2]~(4-)

机译:基于线性聚阴离子[Mn_4(H_2O)_(18)WZnMn _2(H_2O)_2(ZnW_9O_(34))_2]〜(4-)的1D到3D单晶到单晶结构转换

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摘要

A 1D anionic polyoxometalate, [Mn_4(H_2O) _(18)WZnMn_2(H_2O)_2(ZnW_9O _(34))_2]~(4-), undergoes 1D to 3D single-crystal-to-single-crystal structural transformations that are induced by transition-metal cations (Co~(2+) and Cu~(2+)) and solvent molecules. These solid materials present interesting catalytic activity for the oxidative aromatization of Hantzsch 1, 4-dihydropyridines that is dependent on the inserted heterogeneous metal cations.
机译:一维阴离子多金属氧酸盐[Mn_4(H_2O)_(18)WZnMn_2(H_2O)_2(ZnW_9O _(34))_ 2]〜(4-)经历1D到3D单晶到单晶的结构转变,由过渡金属阳离子(Co〜(2+)和Cu〜(2+))和溶剂分子诱导。这些固体材料对Hantzsch 1,4-二氢吡啶类化合物的氧化芳构化表现出令人感兴趣的催化活性,这取决于所插入的异质金属阳离子。

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